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Bowl Fresh Bleach Alternative, Automatic Toilet Bowl Cleaner-05/02/2023
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaPurpose of product.
Usage: Toilet bowl cleanerStructure such as solid, liquid, aerosol etc.
Form: tabletDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 20244044 Park Avenue
Saint Louis MO 63110
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Advanced
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Percent of chemical in preparation.
% Conc.Purpose served by this chemical
FunctionChemical of Concern (CoC)
Chemical of Concern(CoC)Sodium tetraborate anhydrous 001330-43-4 17.5 Cleaning Agent Yes 
CoC List
C10-16 Alkylbenzene Sulfonic Acid 068081-81-2 14.0 Surfactant No Sodium Carboxymethyl Cellulose 009004-32-4 10.0 Binder No Hydroxyethyl cellulose 009004-62-0 10.0 Binder No Sodium perborate monohydrate 010332-33-9 3.75 Oxidizing agent Yes CoC List
Alcohols, C11-14-iso-, C13-rich, ethoxylated 078330-21-9 2.7 Surfactant No Acid Blue 9 003844-45-9 2.5 Colorant No Aluminum sulfate anhydrous 010043-01-3 1.67 Coagulant No Edetate sodium tetrahydrate 013235-36-4 1.0 -- No Sodium sulfate 007757-82-6 -- Viscosity Adjuster No Water 007732-18-5 -- Solvent No Sodium chloride 007647-14-5 -- Thickener No Sodium ferrocyanide 013601-19-9 -- Thickener No Tetrasodium EDTA 000064-02-8 -- Chelating Agent No Citric acid 000077-92-9 -- Preservative No Glycols, polyethylene 025322-68-3 -- Viscosity Adjuster No -
Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :May 02, 2023 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING3* 0 0 -
Warnings
Hazard Statements
Danger. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May damage fertility or the unborn child.
Precautionary Statements
General
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.
Prevention
Wear protective gloves/protective clothing/eye protection/face protection. Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product.
Response
IF exposed or concerned: Get medical advice/attention.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor.
IF ON SKIN: Wash with plenty of water and soap. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse.
IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. Rinse mouth.
Storage
Store locked up.
Disposal
Dispose of contents/container to an approved waste disposal plant. -
Acute health effects
From SDS:
Hazards Identification
Emergency Overview
Danger. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May damage fertility or the unborn child.
Potential Health Effect
Eye Contact: Specific test data for the substance or mixture is not available. Causes serious eye damage. (based on components). Severely irritating to eyes. May cause burns. May cause irreversible damage to eyes.
Skin Contact: Specific test data for the substance or mixture is not available. Causes skin irritation. (based on components).
Inhalation: Specific test data for the substance or mixture is not available. May cause irritation of respiratory tract.
Ingestion: Specific test data for the substance or mixture is not available. Harmful if swallowed. (based on components). Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. -
Chronic health effects
From SDS:
No data. -
Carcinogenicity
No information available. -
Handling information
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Remove contaminated clothing and shoes. Take off contaminated clothing and wash before reuse. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach of children. Store locked up. -
Disposal information
Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation. Do not reuse empty containers. -
California Prop. 65 Warning
This product does not contain any Proposition 65 chemicals.
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First Aid
Eye Contact: Get immediate medical advice/attention. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area.Skin Contact: Wash off immediately with soap and plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists.Inhalation: Remove to fresh air. Get medical attention immediately if symptoms occur.this safety data sheet to the doctor in attendance. Immediate medical attention is required.Ingestion: Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician.
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UN Global Harmonization Classification
